unsaturated ferocene containing nitriles

Author: tatia minadze
Co-authors: –––
Keywords: aldoximes, nitriles, aminonitrile
Annotation:

Transformation of aldoximes FcCH=NOH (1) and Fc-C(Cl)=CH-CH=NOH (2) , (Fc-ferrocenyl) into the corresponding nitriles FcCN (3) and Fc-C(Cl)=CH-CN (4) , were performed by the method, which includes application of PPh3/CCl4 , β-Ferrocenyl-β-aminoacrylonitrile, Fc-C(Cl)=CH-CN, was synthesized by the reaction of 3 with acetonitrile in the presence of KOtBu .